Although many people think of gases and vapors from gasoline or other chemicals as "fume," technically, fume is comprised of very small, solid particles. Since arc welding usually produces only small concentrations of gases, exposure to gases is seldom a concern except in confined areas. Therefore, the issue of secondary gas production will not be specifically discussed here.
Arc welding creates fume as some of the metal boils from the tip of the electrode and from the surface of molten droplets as they cross the arc. This metal vapor combines with oxygen in the air and solidifies to form tiny fume particles. These particles are visible because of their quantity, but each particle is only between 0.2 and 1.0 micron in size. Since fume primarily comes from the electrode, it consists of oxides of its metals, alloys and flux compounds. In steel welding, therefore, fume is primarily iron oxide and oxides of alloys such as manganese and chromium. With plated or coated metals, some of the fume comes from the weld pool as well. This adds oxides of metals from the base material into the fume such as zinc oxide from welding galvanized steels.
Key Point: Welding fume consists of solid metal oxide particles ranging from 0.2 to 1.0 micron, primarily originating from the electrode but also from base materials.